Trace elements and stable isotopic geochemistry of an Early Cambrian chert-phosphorite unit from the lower Yurtus Formation of the Sugetbrak section in the Tarim Basin   总被引：1，自引：0，他引：1  

ChunYan Yao  DongSheng Ma  HaiFeng Ding  XiaoYong Zhang  Hui Huang 《中国科学:地球科学(英文版)》2014,57(3):454-464

A chert-phosphorite unit from the Sugetbrak section in the Tarim Basin was analyzed for rare earth elements (Ce, Eu), redox sensitive proxies, and carbon isotopic compositions (δ¹³C_carb and δ ¹³C_org) in the lower Yurtus Formation of the Early Cambrian period. Redox sensitive element ratios (Th/U, V/Cr, Ni/Co, and V/Sc) were employed to determine the palaeoenvironmental conditions during this period. The ratios indicated that the depositional environment of the chert-phosphorite-black shale unit ranged from suboxic to anoxic. Negative Ce and positive Eu anomalies in the chert-phosphorite assemblages of the studied Yurtus Formation indicated the existence of a redox-stratified ocean, similar to that of South China. Overturn or upward expansion of the deep water-mass probably reached the shallow marine zone after the formation of the Yurtus phosphorites. The characteristics of the negative Ce anomaly may be due to phosphoritic inheritance from the Ce-depleted signature of the overlying water column. Subsequent hydrothermal inputs and reduced detrital supplies of the deep water caused by the upwelling affected certain redox sensitive elements in the sedimentary basin. δ ¹³C_carb and δ¹³C_org negative excursions in the Yurtus chert-phosphorite unit may be related to a transgression phase when episodic basinal upwelling moved ¹²C- and P-rich waters from the pelagic basin floor to the continental shelf. Although carbon isotopic compositions in the Yurtus chert-phosphorite assemblages may have suffered from diagenetic alteration, they can be used to probe diagenetic conditions. Multi-proxy geochemical studies indicated that the δ ¹³C_carb values of the Yurtus chert-phosphorite assemblages might be considered reflections of a predominantly suboxic environment that was subsequently affected by hydrothermal inputs due to the upwelling.  相似文献   

Diagenetic fluid evolution and water-rock interaction model of carbonate cements in sandstone: An example from the reservoir sandstone of the Fourth Member of the Xujiahe Formation of the Xiaoquan-Fenggu area,Sichuan Province,China   总被引：1，自引：0，他引：1  

LIU SiBing  HUANG SiJing  SHEN ZhongMin  Lü ZhengXiang  SONG RongCai 《中国科学:地球科学(英文版)》2014,57(5):1077-1092

Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolution, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios(δ13C = 2.14‰, δ18O = -5.77‰), and was precipitated early. It was precipitated directly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid(δ18O = -3‰), which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios(δ13C = -2.36‰, δ18O = -15.68‰). This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2+, Fe3+ and Mg2+ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the burial process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite cements in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone(δ13C = 1.93‰, δ18O = -6.11‰), demonstrating that the two are from the same source that had a heavier oxygen isotope ratio(δ18O of about 2.2‰). The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different water-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles(lithic quartz sandstone) has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.  相似文献   

Atmospheric Nitrogen and Phosphorus Deposition at Three Sites in Nanjing,China, and Possible Links to Nitrogen Deposition Sources   总被引：1，自引：0，他引：1       下载免费PDF全文

Liying Sun  Yinglie Liu  Jinyang Wang  Mohammad Aslam K. Khalil  Jianwen Zou  Zhengqin Xiong 《洁净——土壤、空气、水》2014,42(11):1650-1659

  相似文献   

澜沧江河流沉积物碎屑锆石U-Pb年龄、Hf同位素组成及其地质意义     

陈雪  陈岳龙  包创  李光琪  闫家盼  李大鹏 《现代地质》2014,28(6):1170-1182

为研究澜沧江沉积物的物质来源及相邻地块的地壳生长和演化规律,利用LA-MC-ICP-MS分析技术,对澜沧江河流沉积物碎屑锆石进行了U-Pb年龄和Hf同位素研究。结果表明：锆石U-Pb年龄主要有5个年龄段,分别是＜177 Ma、201~418 Ma、428~544 Ma、581~1189 Ma和1406~2533 Ma,主要峰值为260 Ma、788 Ma、1 827 Ma和2 474 Ma。其年龄分布特征与北羌塘地块的年龄分布非常一致,说明澜沧江沉积物主要来源于北羌塘地块;结合Hf同位素分析结果,能够反映源区北羌塘地块的形成与演化历史。新太古代-中元古代是北羌塘地块从亏损地幔物质增生的地壳持续生长阶段,它们构成现今北羌塘地块全部地壳物质的78%以上,此后直到0.64 Ga,北羌塘地块的地壳增生作用基本结束。  相似文献   

地表岩石侵蚀速率对宇生核素暴露测年影响的研究     

张志刚  王建  白世彪  徐孝彬  常直杨 《地理科学》2014,34(1):116-121

利用原地生宇生核素测定暴露年代时,通常会假设地貌体侵蚀速率为0。研究表明,该假设会低估地貌体的真实暴露年代。搜集2009~2012年全球不同区域56个岩石样品的宇生核素¹⁰Be测年数据,探讨侵蚀速率为0对于侵蚀速率为0.5、1以及2 mm/ka的样品,在不同暴露尺度上对暴露年代计算的影响幅度。结果表明,对于1×10⁴a尺度的样品暴露年代可能低估约0.5%,1%,2%;对于10×10⁴a尺度的样品可能低估约5%,7%,20%;对于50×10⁴a尺度的样品可能低估约40%,70%甚至100%以上。  相似文献   

中天山天湖东铁钼矿含矿片麻状花岗岩年代学、地球化学和锆石Hf同位素-对于中天山早古生代构造演化的启示     

雷如雄  吴昌志  屈迅  顾连兴  陈刚  吾尔娜  孙洪涛  刘国宁 《吉林大学学报(地球科学版)》2014,44(5):1540-1552

以中天山东段的天湖东铁钼矿含矿花岗岩为例,在LA-ICP-MS锆石U-Pb年代学测定其为早古生代花岗岩（（445.3±4.6） Ma）基础上,通过岩相学、地球化学及锆石原位Hf同位素组成等多方面研究,探讨该岩体的成岩作用及其构造背景。天湖东含矿片麻状花岗岩的主要矿物为斜长石、石英、钾长石,并含少量黑云母和角闪石等。全岩地球化学分析结果表明,该片麻状花岗岩高硅、弱富铝、富钙、富钠而贫钾,ASI值为0.68~0.82,属于准铝质钙碱性花岗岩,总体上富集大离子亲石元素（LILE）Rb、Ba等和轻稀土元素La、Ce、Nd等,而亏损高场强元素Nb、Ta、Ti、Yb等,轻重稀土分异明显,轻稀土分异较为明显,而重稀土分异不明显,表现出典型岛弧岩浆岩的地球化学特征。锆石的ε_Hf(445 Ma)值为-6.31~-1.77,二阶段Hf模式年龄（T_DM2）为1.538~1.825 Ga,表明该花岗岩的源区主要为壳源物质。综合分析上述资料,认为天湖东铁钼矿片麻状花岗岩是由俯冲过程中地壳物质重熔的产物。结合前人的研究和本课题组的新近研究成果认为,在早古生代时,中天山为岩浆弧构造环境,形成一系列的钙碱性岩浆岩,而该岩浆弧的形成可能是受到介于吐哈陆块和塔里木板块之间的古天山大洋在早古生代时期向南俯冲而形成的。  相似文献   

渤海湾盆地古近纪海侵问题研究进展及展望   总被引：10，自引：2，他引：8  

袁文芳  陈世悦  曾昌民 《沉积学报》2005,23(4):604-612

有关渤海湾盆地古近纪是否发生过海侵的问题争论了二十多年,至今尚无定论。尽管“海侵”论者提供了矿物学、岩石学、古生态学以及地球化学等多种标志,但是因为这些标志与标准海相标志比较,都有一定差别,而且至今没有发现确实可靠的海侵通道和明显的海相性递增现象,所以又出现了“海泛”论、“海啸”论和“陆相”论。几种观点长期并存,笔者认为要解决这一问题,可以从四方面入手①深入研究渤海湾盆地的构造背景,推断海侵通道存在的可能性;②进一步厘定已有的海相标志的准确性;③寻求新的、唯一的能区分海陆相成因的证据;④搜集国外在相关层位有类似沉积的地区,进行对比研究,并探索其成因。  相似文献   

安徽巢湖地区下三叠统综合层序   总被引：17，自引：2，他引：15  

童金南  赵来时  左景勋  Hans J.Hansen  Yuri D.Zakharov 《地球科学》2005,30(1):40-46

印度阶一奥伦尼克阶界线的全球层型候选剖面之一位于安徽巢湖地区;巢湖地区的下三叠统也是国际上同期地层中生物地层序列最有代表性、多重地层学手段应用齐备、研究效果最好的地层序列之一。根据巢湖地区3条代表性下三叠统剖面的岩石地层、生物地层和碳同位素地层的最新研究成果归纳出本区早三叠世综合地层序列,作为区域地层对比研究的标准．巢湖的下三叠统明确包含8个牙形石带和6个菊石带。它们具有区域甚至全球对比意义;巢湖地区早三叠世碳同位素δ^13Ccarb的演变呈现2个显著的漂移周期,这种有特色的碳同位素漂移,不仅具有地层学价值,而且可能对于三叠纪初的生物复苏和生态系演变具有指导意义．在综合地层序列基础上,将3条剖面的古地磁学研究成果链接,形成了巢湖地区完整的早三叠世磁性地层序列,包括5个主要的正向极性带和5个反向极性带,这也是目前在本区乃至华南获得的最完整的早三叠世磁极性序列之一．这些为该区域乃至全球相关地层研究树立了一个基本格架。  相似文献   

大别造山带大陆深俯冲和折返过程中壳-幔相互作用信息--来自大理岩铅同位素的证据   总被引：1，自引：1，他引：0  

刘富  周汉文 《地质科技情报》2005,24(1):14-18

对大别造山带不同产状大理岩的铅同位素研究表明,红安群王家店和双河大理岩分别经历过高压和超高压变质作用,具有较高的铅同位素变化范围和高的放射性成因铅,反映了上地壳铅同位素的特征;新店大理岩的铅同位素比值和变化范围很小,具有EM1型地幔铅同位素特征,表明有地幔铅同位素特征的记录;而位于剪切带的方高坪大理岩的铅同位素除了n(206Pb)/n(204Pb)值更高外,与新店大理岩的铅同位素特征相似,记录了放射性铅同位素的大量加入或丢失,导致本来具有与双河大理岩类似的铅同位素特征变得不明显.这些结果均表明大陆深俯冲及其折返过程对大理岩铅同位素组成的改造是相当复杂的.  相似文献   

Extreme Enrichment of Tellurium in Deep-Sea Sediments   总被引：2，自引：0，他引：2  

LI Yanhe  WANG Yimin  SONG Hebin  and YUE Guoliang  Laboratory of Isotope Geology  Ministry of Land  Resources  Beijing  E-mail: lyh@mx.cei.gov.cn Institute of Mineral Resources  Chinese Academy of Geological Sciences  Beijing  National Geoanalysis Center  Beijing 《《地质学报》英文版》2005,79(4):547-551

Tellurium is a sort of scattered rare element on the earth. Its concentration is very low in earth＇s crust, only 1.0 ng/g. However, it has extremely high abundance in Co-rich crusts, marine polymetallic nodules, deep-sea sediments and aerolites. To find out the origin of tellurium enrichment in deep-sea sediments, we analyzed and compared tellurium concentrations and helium isotope compositions in the magnetic parts and those in the bulk parts of deep-sea sediments. The result indicates that the helium content, 3He/4He ratio and tellurium concentration are obviously higher in the magnetic parts than those in the bulk parts. The 3He abundance varies synchronously with the tellurium concentration. 3He and Te have a distinct positive correlation with each other. It is the first time that the paper brings forward that the extreme enrichment of tellurium in deep-sea sediments, like helium isotope anomalies, probably results from the input of interplanetary dust particles （IDPs）. Similarly, the extreme enrichment of tellurium in marine polymetallic nodules and Co-rich crusts is possibly related to IDPs.  相似文献